1. Are you sure that the water heater in the rig is set up to heat water via either electric or propane?
2. If the switch to which you refer is for the gas heating, there should also be a red light next to or near the switch. This red light comes on when ignition is initiated and then goes out when the propane burner is working properly. In other words, if there isn't a red light next to the switch it may mean that the switch is for the electric heating element.
3. Have you contacted the manufacturer? They might know where they put/hid the switch in question. Any owner's manuals?
4. Often, manufacturers put such switches in or near the bathroom/shower area so that one can get the water up to temp prior to turning on the shower. If you've got an electric switch, it could well be in that part of the rig. It is possible that the switch is in the kitchen area, near the sink. I owned a travel trailer where the manufacturer had put the water heater electric switch inside a cabinet over the kitchen counter. If the rig has a panel area where the manufacturer has grouped holding tank level gauges, the thermostat and other device controls, such a switch could be in that area, but I'm sure you would have seen that.
5. I have seen units that have the switch outside, behind the door to the water heater. Take off the door and see if there is a little black switch on the surface of the water heater that faces out.
6. I doubt that any of this will help but not knowing the rig that's the best I can do. Hopefully someone with a 5th wheel like yours will respond.